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Thermal and chemical effects of current

Thermal effects:

Joule’s law of heating:

“The heat produced in a conductor is:

(1) Directly proportion the square of current passing through the conductor,(H ∝ I²) keeping R and t constant;

(2) Directly proportion to the resistance of the conductor (H ∝ R) keeping I and t constant;and

(3)Directly proportional to the time of flow of current (H ∝ t) keeping I and R constant.”

Mathematical form of Joule’s law:

   H=I²Rt

Verification of Joule’s law:

The above laws of heating by electric current can be verified in the laboratory using a joule’s calorimeter.

To verify the above laws,heat is generated in a resist;coil R which is enclosed in a copper calorimeter containing water to about two thirds of its volume.The ends of R are connected to finding terminals fixed to the lid.The calorimeter is enclosed in wooden box to minimize the logs of heat.A is the ammeter to measure the current and V is the voltmeter to measure the potential difference across R.A rheostat is connected in the circuit to alter the current.

(a):Let W be the total water equivalent of the calorimeter (including the calorimeter,stirrer and water ) and T1 the initial temperature.A current of I1 amperes is passed for a known interval of time (about 15 to 20 minutes) and the final temperature T2 (after correcting for the loss of heat by radiation ) is noted.Then,the quantity of heat produced =HI=W[θ1 -θ2].Similarly,the experiment is repeated with different values of current I2,I3 etc.( after cooling the calorimeter to the initial temperature) and the corresponding quantities of heat produced H2,H3 etc are noted,keeping R and t constant.

It will be found that:

\frac { { H }_{ 1 } }{ { { I }_{ 1 }^{ 2 } } } =\frac { { H }_{ 2 } }{ { { I }_{ 2 }^{ 2 } } } =\frac { { H }_{ 3 } }{ { { I }_{ 3 }^{ 2 } } } \quad i.e\quad \frac { { H } }{ { { I }^{ 2 } } }

(b):To verify the second law ,the same time t through different resistance coils R1,R2,R3 etc and the corresponding quantities of heat H1,H2,H3 etc are calculated.

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Then it will be found that:

\frac { { H }_{ 1 } }{ { { R }_{ 1 } } } =\frac { { H }_{ 2 } }{ { { R }_{ 2 } } } =\frac { { H }_{ 3 } }{ { { R }_{ 3 } } } \quad

(c)To verify the third law,the same current I is passed through the same resistance coil R,for different intervals of time and the quantities of heat produced H1,H2,H3 etc in each case are determined .It will be found that:

\frac { { H }_{ 1 } }{ { { I }_{ 1 } } } =\frac { { H }_{ 2 } }{ { { I }_{ 2 } } } =\frac { { H }_{ 3 } }{ { { I }_{ 3 } } } \quad

What are applications of heating effect of electric current?

1:Safety fuse:A safety fuse is a short piece of wire of low melting point.This is made of an alloy of tin and lead.The fuse wire is connected in series with the electrical installation and,when the current in the circuit exceeds the rated value,the fuse wire gets heated to a temperature higher than its melting point.The wire melts and the electric circuit is cut off.The temperature to which the wire gets heated is directly proportional to the cube of the radius.Thus the temperature depends only on the current flowing through the wire and its radius irrespective of its length.

2:Electric heater or stove,electric Radiators and electric Iron.All these are based on the same principle that is produced when electric current flows through a wire.These contain coils of nichrome (an alloy of nickle and chromium) and large currents of the order of 3 to 5 amperes can be passed through them.In the case of an electric heater working 220 volts and consuming a power of 1000 watts,the current through the coils will be 4.55 amperes.The resistance of the coil will be 48.4 ohms.In the case of electric radiators ,the coil is placed along the axis of a parabolic metallic reflector or at the focus of a concave reflector.

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Seebeck effect:seebeck effect of current

If two metal wires or strips A and B made of dissimilar metals are joined at the ends to form two junctions shown in figure,then such a device is called thermocouple.

If two junctions of a thermocouple are kept at different temperature,an electric current will be induced in the loop.This effect is called Seebeck effect,and emf so developed is known as Seebeck emf or Thermo emf.The magnitude and direction of the emf depends upon the metals used and the temperature difference between hot and cold junctions.The thermo emf induced is given by:

E = αμ + βθ²/2  

Where θ is the temperature difference between hot and cold junctions.effect of temperature of cold junction

Note that curve is parabolic.Note that natural temperature Remains unchanged when temperature of cold junction is curved.

At neutral temperature emf is maximum.

Peltier effect:

The converse of Seebeck effect is Peltier effect.If current is passed through a thermocouple or an external battery is applied across the two junctions of a thermocouple then one of the junctions becomes hot and other gets cold.The heat liberated or absorbed at one of the junctions is given by:

ΔH/ΔQ=πAB ,Which is Peltier emf.Where ΔQ is charge transferred.

Peltier coefficient is the amount of heat liberated per second when 1-A of current is passed through a thermocouple.

Thomson effect:

thomson effect

If two sections of a conductor are at different temperatures then emf is developed between these two sections.This effect is known as “Thomson effect”.

 

Applications of thermal effects of current:

  • Electro power generation
  • Refrigeration
  • Detection and heat radiation
  • Measurement of temperature

Chemical effects of current:

Voltmeter or coulomb meter:

The vessel in which electrolytes is carried out.It is also called electrolytic cell.

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Electrolyte:

An ionic compound in aquas solution or molten state is called an electrolyte.

Electrolysis:

On passing current through an electrolyte,chemical changes occur in electrolyte and substances are liberated at the electrodes.This process is called electrolysis.

Faraday’s laws:

First law:

The mass of a substance liberated on electrode is proportional to the current passed through it and proportional to the time for which current is passed.

                                              m ∝ I

and                                          m ∝ t

Or                                           m=zIt

Where z is called electrochemical  equivalent.Since It = Q;  m=ZQ

Z =Chemical equivalent in gram/1 Faraday

Faraday (F):It is the amount of charge on 1 mole of electrons =96485 C.Practically we use 1F =96500 c.

Second law:

If same quantity of electricity is based through different electrolytes,the mass of the substances deposited at the respective cathodes are directly proportional to the chemical equivalent.

Note 1 Faraday of charge will liberate 1 gram equivalent any substance during electrolysis.

Electrolytic cell or voltmeter may be used to measure current more accurately than ammeters.

Back emf:

It is the potential difference opposite to the thermal emf setup due to accumulation of ions around the double electrodes.The back emf depends upon the nature of the electrodes and concentration of ions.

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